The sixth-form college offers a wide range of A level subjects, along with GCSEs, retake programmes, and one-year intensive courses. Lessons are taught in small groups of typically fewer than ten students, creating an interactive setting where each pupil is known individually. The academic structure includes weekly timetables designed for flexibility, personalised academic targets, frequent assessments, and one-to-one meetings with personal tutors to track progress and build effective study habits.

The college places a strong emphasis on university preparation. Students benefit from extensive UCAS support, including personal statement guidance, interview practice, admissions test preparation, and specialist pathways for competitive courses such as medicine, law, and engineering. Facilities at the South Kensington campus include modern science laboratories, art and photography studios, a digital learning suite, and quiet study areas. Although MPW does not operate traditional school sports teams, it offers an enrichment programme that includes fitness, clubs, societies, cultural events, and academic lectures. Pastoral support is a major strength, with a focus on wellbeing, motivation, and structured academic discipline.